Beilstein J. Nanotechnol.2018,9, 384–398, doi:10.3762/bjnano.9.38
.
Materials
Copper(II) carboxylate compounds with tert-butylamine of the general formula [Cu2(t-BuNH2)2(µ-O2CR)4], where R = CnF2n+1, n = 1–6, were obtained in the reaction of copper(II) perfluorinatedcarboxylates with tert-butylamine, which was in situ generated from tert-butyl isocyanate [34]:
The
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Figure 1:
A schematic structure of investigated molecules (left) [Cu2(µ-O2CC2F5)4], (right) [Cu2(EtNH2)2(µ-O2...
Beilstein J. Nanotechnol.2018,9, 57–65, doi:10.3762/bjnano.9.8
for ligands fragmentation allow one to envisage the use of the two precursors for FEBID studies.
Keywords: amines; copper(II); electron-stimulated desorption; FEBID precursors; HREELS; low-energy electrons; perfluorinatedcarboxylates; Introduction
The high electrical conductivity of copper makes it
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Figure 1:
Schematic view of compound B, [Cu2(EtNH2)2(μ-O2CC2F5)4]; (H in white, C in grey, N in blue, O in re...